Step1: Prepping BartPE:
First we’ll prep the USB drive we’ll be using for booting.
This is by far the largest step in the process, though it shouldn’t be
difficult for anyone to follow. It requires a functional Windows system.
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Download BartPE builder from http://www.nu2.nu/pebuilder/
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Install BartPE. We’ll be assuming that you install to C:\pebuilder.
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Start PE Builder from the Start Menu. Point "Source:" to the location of your Windows XP setup files containing SP3.
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Make sure the "Output:" is set to "BartPE".
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Set "Media output" as "Create ISO image" and filename as "c:\pebuilder\pebuilder.iso".
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Hit "Build".
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When it's done building, image file "c:\pebuilder\pebuilder.iso" should be created properly.
Step2: Create XP Bootable USB Drive: